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Ozonation

Advanced treatment of textile dyeing wastewater through the combination of moving bed biofilm reactors and ozonation

Pages 1589-1597 | Received 01 Oct 2015, Accepted 10 Mar 2016, Published online: 18 May 2016
 

ABSTRACT

A four-stage lab-scale treatment system [anaerobic moving bed biofilm reactor (MBBR)-aerobic MBBR-ozonation-aerobic MBBR in series] was investigated to treat textile dyeing wastewater. The MBBRs were operated in a continuous horizontal flow mode. To determine the optimum operating conditions, the effect of hydraulic retention time (HRT) and ozonation time on pollutant removal were analysed by continuous and batch experiments. The optimum operating conditions were found to be 14 h HRT for both anaerobic and no. 1 aerobic MBBRs, 14 min ozonation time and 10 h HRT for no. 2 aerobic MBBR. The average influent concentrations of chemical oxygen demand (COD), suspended solids (SS), ammonia and colour were 824 mg/L, 691 mg/L, 40 mg/L and 165°, respectively. Under these conditions, the average effluent concentrations of COD, SS, ammonia and colour were 47 mg/L, 15.2 mg/L, 5.9 mg/L and 6.1°, respectively, corresponding to total removal efficiencies of 94.3%, 97.8%, 85.3% and 96.3%, respectively. The final effluent could meet the reuse requirements of textile industry. The anaerobic MBBR process improved the biodegradability of the raw wastewater, while the two aerobic MBBRs played an important role in removing COD and ammonia. The ozonation process enhanced the biodegradability of no. 1 aerobic MBBR effluent, and finally, deep treatment was completed in no. 2 aerobic MBBR. The combined process showed a promising potential for treatment of high-strength dyeing wastewater.

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