Adsorption of Phenol from Aqueous Systems onto Spent Oil Shale

Abstract

To evaluate its ability to remove phenol from aqueous solution, Jordanian “spent” oil shale, an abundant natural resource, has been used in an experimental adsorption study. Equilibrium of the system has been determined at three temperatures: 30, 40, and 55C. The resulting experimental equilibrium isotherms are well represented by Frendlich, Langmuir, and Redlich-Peterson isotherms. The relevant parameters for these isotherms, as regressed from the experimental equilibrium data, are presented. Effects of solution pH (in the range of 3–11), in addition to effects of three inorganic salts (KI, KCl, and NaCl, each at 0.1, 0.01, and 0.005 M), on the equilibrium isotherms have been experimentally investigated. The effects of pH in the presence of KI and NaCl were also investigated for a possible interaction between salts and solution pH. The initial concentration of phenol in the aqueous system studied ranges from 10 to 200 ppm. Experimental results show that while an acidic solution has no effect on the adsorption capacity of spent oil shale to phenol, a highly basic solution reduces its adsorbability. No sound effect was observed for the inorganic salts studied on the adsorption of phenol on spent oil shale. The experimental results show that there is no interaction between the pH of solution and the presence of salts. In spite of its ability to remove phenol, spent oil shale showed a very low equilibrium capacity (of an order of magnitude of 1 mg/g). Should the adsorption capacity of the shale be improved (by different treatment processes, such as grafting, surface conditioning), results of this study will find a direct practical implication in serving as “raw” reference data for comparison purposes. salts. The experimental results show that there is a certain degree of coupling between the pH of a solution and the presence of KI salt. Other salts have shown no interaction with the solution pH. The experimental results are explained in terms of the degree of ionization of the adsorbate which is controlled by the pH of the solution.

Key Words. :

• Adsorption
• Oil shale
• Phenol
• Salts
• KCl
• KI
• NaCl
• pH