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Ozone: Science & Engineering
The Journal of the International Ozone Association
Volume 14, 1992 - Issue 1
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Original Articles

Numerical Simulations of Aqueous Ozone Decomposition

Pages 33-49 | Received 12 Sep 1990, Accepted 15 Jun 1991, Published online: 25 Jul 2008
 

Abstract

The decomposition of ozone in basic aqueous solutions was simulated on the basis of two previously reported detailed mechanisms. According to the calculations, the mechanism given by Tomiyasu, Fukutomi and Gordon5 is an appropriate model for the ozone decomposition, both in the presence and the absence of hydrogen peroxide and/or carbonate ion in basic solution. On the basis of this mechanism the main chain carrier is the ozonide ion radical .

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