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Journal of Dispersion Science and Technology Volume 23, 2002 - Issue 1-3
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Original Articles

The pH-Dependent Surface Activity of a Hydrocarbon/Fluorocarbon Catanionic Surfactant for Water/Hydrofluoroether Microemulsions: The Characterization of a New Acid/Soap Complex

Jimmie R. Baran Jr. Advanced Materials Technology Center, 3M Company, 3M Center, Building 201-1W-28, Maplewood, Minnesota, 55144
,
Emily L. Decker Advanced Materials Technology Center, 3M Company, 3M Center, Building 201-1W-28, Maplewood, Minnesota, 55144
&
Heather N. Wilcox Advanced Materials Technology Center, 3M Company, 3M Center, Building 201-1W-28, Maplewood, Minnesota, 55144
Pages 23-28 | Received 10 Jun 2001, Accepted 25 Aug 2001, Published online: 12 Feb 2010
 
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ABSTRACT

The pH sensitivity of a hydrocarbon/fluorocarbon catanionic surfactant is investigated. The catanionic surfactant is sensitive to low pH, which results in the precipitation of an acid/soap complex. This complex is identified by IR, NMR and confirmed by x-ray crystallography.

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