Synthesis and Evaluation of Ethoxylated Alkyl Sulfosuccinates as Oil Spill Dispersants

Abstract

The surface properties particularly, Krafft point, foam stability and emulsion stability for the synthesized series of ethoxylated sodium monoalkyl (octyl-, dodecyl-, and cetyl-) sulfosuccinate surfactants were investigated comparing with those of sodium dioctyl sulfosuccinate. The prepared surfactants were evaluated as oil spill dispersants using screen test method. The results show that, the ethylene oxide units in the mixed moiety surfactant system (anionic–nonionic) effect on the depression of the Krafft point. Also, the increasing of ethylene oxide units in the prepared surfactants decreases the foam ability of these surfactants. The results of emulsion stability show that, the increasing in ethylene oxide units owing to the emulsion stability decreases. The prepared surfactants show a dispersion capability at different content of ethylene oxide units (9, 14, 23, and 90) and at different concentrations. The dispersion capability for these surfactants in the sea water is better than in the fresh water. The results show that, the increase of ethylene oxide units increases the dispersion efficiency of the synthesized surfactants.

Keywords:

• Ethoxylated sodium monoalkyl sulfosuccinates
• oil spill dispersants
• surface properties

Notes

∗SOR = surfactant oil ratio, where in oil is 100 μL, A: very good dispersability; B: good dispersability; C: bad dispersability; D: very bad dispersability.

∗SOR = surfactant oil ratio, where in oil is 100 μL, A: very good dispersability; B: good dispersability; C: bad dispersability; D: very bad dispersability.

∗SOR = surfactant oil ratio, where in oil is 100 μL, A: very good dispersability; B: good dispersability; C: bad dispersability; D: very bad dispersability.