Preparation and Characterization of Nanocrystalline Fe-Doped TiO₂ Film on Different Substrates and Its Application in Degrading Dyeing Water

Abstract

TiO₂ and Fe-doped TiO₂ thin films were prepared on the substrates (glass plates and glass microballs) after dipped in colloid and calcined at 500°C. The films have been characterized by UV-absorption, x-ray diffraction and atomic force microscopy (AFM). The investigated Fe-doped TiO₂ (A nominal 10 wt% Fe₂O₃ was impregnated) thin films were obtained by sol-gel method. The characterization results suggest that the calcined thin films primarily consist of TiO₂ anatase. And the light absorption curve of the TiO₂ films modified with Fe showed that red shift had happened by the dope of Fe. TiO₂/beads as photocatalyst were used to degrade the simulated dyeing water which contains reactive deep-blue dye (K-R). Through the degradation experiment, we found that the dope of Fe promoted the photocatalytic activities. The results showed that the dyeing water can be decomposed more effectively by the photocatalytic oxidation of Fe/TiO₂ film on glass micro-balls than glass plates.

Keywords:

• Dyeing wastewater
• Fe doped
• glass micro-balls
• photocatalytic oxidation
• sol-gel process
• titanium dioxide

Acknowledgments

This work is supported by the Natural Science Foundation of Qingdao University of Science and Technology (Grant No. 03Z02).