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Original Articles

Dilational Viscoelasticity of the Zwitterionic Gemini Surfactants with Polyoxyethylene Spacers at the Interfaces

, , , &
Pages 1537-1546 | Received 27 Jun 2010, Accepted 28 Jul 2010, Published online: 24 Oct 2011
 

Abstract

The dilational viscoelasticity of zwitterionic gemini surfactants C8ExNC12 with polyoxyethylene spacers at the water-air and water-decane interfaces were investigated by oscillating barriers method. The experiments were carried out at different concentrations with an accessible frequency range of 0.005 to 0.1 Hz. Interfacial tension relaxation method was employed to obtain dilational parameters in a reasonably broad frequency range. Experimental results show that the values of dilational elasticity and viscosity of C8ExNC12 are larger than those of common nonionic surfactants, such as T × 100, and the dilational viscoelasticity at the water-decane is close to that at the water-air interface on the whole. The results may be attributed to Coulombic attraction, and the possible schematic diagrams of adsorbed molecules with different polyoxyethylene spacers at the water-air and water-decane interfaces are proposed. We also analyzed C8ExNC12 from the results of relaxation experiments and Cole-Cole plots.

Acknowledgements

The authors are thankful for the financial support from the National Science & Technology Major Project (2011ZX05011-004), National High Technology Research and Development Program (2008AA092801), and the Knowledge Innovation Program of the Chinese Academy of Sciences (KJCX1-YW-21-03) of China.

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