A comprehensive study for selective removal of Cr(VI) by asymmetric imidazolium bromide salts as environmentally-friendly extractant

ABSTRACT

The study was to determine selective removal and recovery of Cr(VI) from acidic media by solvent extraction (SX) using asymmetric imidazolium-based room temperature imidazolium bromide salts (ARTILs) as the extractants. The relevant parameters on the extraction and the stripping of Cr(VI) were investigated to identify optimum conditions. The optimum conditions were determined as equilibration time 5 minutes, acid concentration and type 0.5 mol/L H₂SO₄, stirring speed 1200 rpm, extractant concentration and type 0.5 mol/L ARTIL5, phase ratio 2.0 and stripping reagent type, and concentration 2.0 mol/L NH₃. In optimum conditions, decyl substituted ARTIL was best in extraction process about 99.7% of extraction rate, whereas moderately hydrophobic pentyl substituted ARTIL was best in stripping process about 70.0% of stripping rate. Also, the optimized process was found as so selective toward Cr(VI) in the presence of the other metal ions with an environmental-friendly liquid–liquid–based SX method.

GRAPHICAL ABSTRACT

KEYWORDS:

• Asymmetric imidazolium bromide salts
• CR(VI) removal
• room temperature ionic liquids
• solvent extraction

Acknowledgments

All experimental works were conducted in Çankırı Karatekin University Research Laboratory. The author thanks all the supporters for their precious contributions.

Additional information

Funding

In this study, the financial support was provided by The Scientific and Technological Research Council of Turkey (TUBITAK), Project No. 112T806.