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Articles

Selective recognition of Fe3+ and Cr3+ in aqueous medium via fluorescence quenching of graphene quantum dots

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Pages 250-255 | Received 09 Feb 2018, Accepted 14 Apr 2018, Published online: 08 Oct 2018
 

Abstract

Graphene quantum dots (GQDs) have been prepared from graphene oxide (GO) and characterized by standard analytical techniques. The size of the prepared GQDs ranges from 2-10 nm. Aqueous dispersion of GQDs exhibited excitation-dependent emission behavior. Emission intensity of the aqueous dispersion found stable for the examined duration of about four months. GQDs exhibited selective recognition of Fe3+ and Cr3+ out of various common ions such as alkali, alkaline-earth and transition metal ions in aqueous medium through fluorescence quenching. The lower limit of detection of Fe3+ is 1 µM and that of Cr3+ is 4 µM.

Graphical Abstract

Acknowledgements

Author V. Kulshrestha is thankful to SERB, Department of Science and Technology, New Delhi, for providing financial support. Authors are also thankful to Analytical Discipline and Centralized Instrument facility, CSMCRI, Bhavnagar for instrumental support. Authors are thankful to the anonymous reviewers for their suggestions/comments to improve the paper.

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