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Original Articles

ADSORPTION AND INTERFACIAL, TENSION IN EMULSION

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Pages 149-158 | Received 14 Oct 1984, Published online: 27 Mar 2007
 

ABSTRACT

This report is an attempt to study adsorption and reduction of interfacial tension caused by adsorption of nonionic ethoxylated nonyl phenols in emulsion. In order to study these phenomenon a method for estimating adsorption and interfacial tension in emulsion was developed. It has been found, in contrast to a concept which appears in literature, that there is no correlation between values of interfacial tension as measured in emulsified and separated oil-water systems. Yet, there seems to be a significant correlation between adsorption values as measured in emulsified and separated oil-water systems. In addition it has been found that the values of maximum adsorption of the emulsifiers as measured in the separated oil-water system correlate linearly with HLB values of these emulsifiers. Such correlation may indicate possible dependance of HLB values on emulsifier's adsorption to the interface.

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