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REGULAR CONTRIBUTED PAPERS

CARBON-13 NMR INVESTIGATIONS OF NONIONIC SURFACTANTS IN NONPOLAR SOLVENTS

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Pages 339-355 | Received 01 Apr 1984, Published online: 28 Mar 2007
 

ABSTRACT

The method recently proposed for the cmc determination in aqueous solutions of nonionic surfactants by 13 C NMR spectroscopy has been applied to solutions in heptane containing increasing amounts of water. It is possible to detect, at a water content of ca. 1.5 molecules per surfactant molecule, the formation of micelles, therefore of aggregates different from those observed, with the help of other techniques, in anhydrous heptane.

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