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Original Articles

PHASE BEHAVIOR OF BRANCHED TAIL ETHOXYLATED CARBOXYLATE SURFACTANT/ELECTROLYTE/ALKANE SYSTEMS.

, , , &
Pages 157-172 | Published online: 27 Apr 2007
 

ABSTRACT

This paper describes the effect of pH on phase behavior of branched tail EO carboxylate surfactants in electrolyte/ alkane microemulsion system3 which are of possible pertinence to enhanced oil recovery. The pH of the aqueous surfactant solutions was found to have a considerable effect on the salinity requirement for middle phase microemulsion formation. At 70 and 60°C alcohol-free optimal three phase microemulsion systems are formed with all alkanes studied over the entire pH range of 6-12. At lower temperatures and. higher pH values, liquid crystals were found to form in systems which contained lower molecular weight alkanes.

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