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Original Articles

SYNTHESIS, IDENTIFICATION AND SURFACE ACTIVITY OF 2-AMINE-2-DEOXY-3-O-n-OCTYL-D-GLUCOPYRANOSE HYDROCHLORIDE

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Pages 259-269 | Received 27 May 1986, Published online: 27 Apr 2007
 

Abstract

The synthesis and identification of this product are described. Variations of surface tension of its aqueous solutions versus concentration (ranged between 3 and 95 mmol/L) and temperature (ranged between 20.0 and 47.5°C) are studied.

The isothermal plots of surface tension versus the logarithm of the concentration show a continous decrease, with a sharp change of slope at a concentration about 6.5 mmol/L, for all the studied temperatures. A second change of slope, less pronounced, appears for a higher concentration. This concentration value increases from 28 to 42 mmol/L when temperature is raised from 20.0 to 47.5°C.

The changes of slope can be attributed mainly to micellization of neutral amine molecules resulting from hydrolysis of surface active cations, which present a weak electrolytic character.

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