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Original Articles

STUDIES OF GELATIN-STABILISED MAGNETIC PARTICLES. USE FOR DISPERSIONS IN POLAR AND NON-POLAR ORGANIC SOLVENTS

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Pages 479-490 | Received 22 Jan 1991, Accepted 10 Apr 1992, Published online: 27 Apr 2007
 

ABSTRACT

Gelatin-stabilised magnetite particles with diameters less than 60A and having a narrow size distribution are prepared as dispersions in water using a one-stage process. Dilution studies and studies of viscosity, pH changes and oxidation of the fluids are reported. Gelatin markedly improves the stability of aqueous fluids to aerial oxidation. Denaturation of the polypeptide chains with a strong base causes flocculation of the magnetic particles, which after treatment with oleic acid etc. may be redispersed in water and in non-polar organic liquids (eg.toluene). Dilution stable fluids are produced incorporating up to 30% by weight of magnetic material.

Treatment of aqueous gelatin-stabilised fluids with sodium dodecylsulfate causes complexation between the anionic surfactant and coordinated gelatin, and produces flocculation of the particles. The magnetite is re-dispersed in polar organic solvents (e.g. ethanol), but not in non-polar organic solvents.

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