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Original Articles

KINETIC EFFECTS OF SURFACTANT / POLYMER MIXTURES UPON ACIDIC HYDROLYSIS OF HYDROXAMIC ACIDS

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Pages 1635-1646 | Received 29 Mar 1999, Accepted 15 May 1999, Published online: 03 May 2007
 

ABSTRACT

The influence of surfactant / polymer (polyethylene glycol, PEG, mol. wt. = 400) mixtures upon the acidic hydrolysis of two N-substituted hydroxamic acids, i.e., R(CO). N(OH)R' : R = C6H5, R' = C6H5;4-CH3C6H4 has been studied using cationic (CTAB, TTAB and CPC) and nonionic (TX-100 and Brij-35) surfactants. An inhibitory effect was observed. The results have been explained by Porinoy - Menger model. The critical aggregation concentration and polymer saturation point of the corresponding systems have also been measured with the conductivity and surface tension methods.

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