An Explanation of the Relative Oxygen and Carbon Monoxide Affinities of Some Iron(II) Porphyrin Complexes: Comments on Inorganic Chemistry: Vol 1, No 4

Comments on Inorganic Chemistry

A Journal of Critical Discussion of the Current Literature

Volume 1, 1981 - Issue 4

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Abstract

The selectivity of O₂ and CO binding of model iron(II) porphyrins is explained on the basis of the number of atoms which connect the porphyrin plane to the top of a cap or a strap. Examples are discussed which discriminate against CO, against both CO and O₂, and the unique example which discriminates against O₂.

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An Explanation of the Relative Oxygen and Carbon Monoxide Affinities of Some Iron(II) Porphyrin Complexes

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An Explanation of the Relative Oxygen and Carbon Monoxide Affinities of Some Iron(II) Porphyrin Complexes

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