Experimental Approaches to Measurement of Intramolecular Electron Transfer Rates

Abstract

Various techniques used for the measurement of intramolecular electron-transfer rales in inorganic systems are considered, and recent applications are described. The methods include electron paramagnetic resonance, Mossbauer spectroscopy, nuclear magnetic resonance, vibrational spectroscopy, dielectric relaxation, pulse radiolysis, photochemistry, electrochemistry, and chemical approaches.