Hollow glass bubbles etched with tunable sizes of through-holes

Abstract

Hollow glass bubbles (HGBs) with through-holes at micron level were fabricated by etching them using diluted 1% hydrofluoric acid (HF) solution in a specially designed reaction system. In this study, the function of each component in the system was carefully investigated and improved to realise the controllable etching process. Various parameters were investigated to explore the optimal etching condition. Highest gross yield of about 85% and effective yield of about 50% were obtained at the optimised etching condition. A separating method was proposed to separate the etched HGBs with different hole sizes with the help of reduced pressure. After separation, HGBs with hole size at sub-micron level, less than 10 µm, and bigger than 10 µm, were achieved. The well-etched HGBs can be used as universal containers to store both reactive and inactive chemicals for applications in self-healing materials, biochemical engineering, and energy industry.

Keywords:

• Hollow glass bubbles (HGBs)
• etching
• through-hole
• yield
• separation

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

Yang greatly acknowledges the partial financial support from HKUST Start-up Fund (R9365). Zhang is grateful to the support from the Key Program of National Natural Science Foundation of China [Grant No. 51435005], the National Instrumentation Program [Grant No. 2012YQ230043], the Science and Technology Program of Guangzhou, China [Grant No. 201607010240], and the Science and Technology Planning Project of Guangdong Province, China [Grant No. 2015B090904004].