Abstract
Three banana-shaped achiral compounds, derivatives of 4,6-dichloro-1,3-phenylene bis-[4-(4-n-octyloxyphenyliminomethyl) benzoate], were synthesized by varying the substituent (X = H, F and Cl). Their mesomorphic properties were investigated by differential scanning calorimetry, polarizing optical microscopy, and X-ray analysis. The compound with X = H exhibited an enantiomeric nematic phase. The compounds with X = F and Cl formed a nematic phase on heating, while on cooling they formed a nematic phase at high temperature and a smectic A phase at a lower temperature (monotropic). A schematic representation of the mesophase structures for the compound with X = F is also illustrated.