Crystal and molecular structures of four model compounds for liquid crystal dimers with a methylene spacer of various lengths

Abstract

The crystal and molecular structures of four model compounds for liquid crystal dimers namely, 4,4‐[octyl]bis‐acetophenone (B(AcP)8), 4,4‐[heptyl]bis‐acetophenone (B(AcP)7), 4,4‐[hexyl]bis‐acetophenone (B(AcP)6), and 1,1‐(1,6‐hexyldion)bis‐benzene (DP6D), have been determined in order to gain an insight into observed differences in the textures of liquid crystalline phases of compounds with odd and even methylene spacers. All four compounds exhibit extended conformations with an all‐trans conformation of the methylene chain but a twist between phenyl rings of about 125°, except DP6D for which the benzene groups lie in plane with the methylene chain. Half a molecule is necessary to represent the asymmetric unit of compounds with even numbers n of methylene groups in the spacer and belong to centrosymmetric space groups. The model compound with an odd value of n is non‐centrosymmetric and shows another type of packing arrangement which may cause different textures and behaviour for dimesogenic compounds in the liquid crystalline state.

Notes

^aτ(C14–C15–C16–C17).

^bτ(C14–C15–C16–C21).

^cτ(C18–C19–C22–C23).

^dτ(C5–C6–C16–C17).

^e l(O1..O2).

^f l(C1..C23).

^gτ(C3–C4..C4′–C3′).

^h l(H1..H1′).