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Original Articles

Synthesis and mesomorphic properties of some new chiral thiobenzoates containing three rings

Pages 195-211 | Accepted 18 Sep 2006, Published online: 28 Feb 2007
 

Abstract

Six new compounds with chiral terminal chains and three rings bridged via the –COS– and –COO– groups have been synthesized. Three of them belong to series A and have two benzene rings and one bicyclo[2,2,2]octane, while the remaining three come from series B, where all three are benzene rings. Series A compounds share a characteristic feature of two smectic phases: SmA* and SmB*, whereas mesogens from the B series exhibit only the one SmA* phase.

Acknowledgements

Prof. Jan Przedmojski, Warsaw University of Technology, Poland is thanked for X‐ray measurements. I would like to thank Wojciech Zając for discussions during preparation of the manuscript. This work was partly supported by the Polish Ministry of Scientific Research and Information Technology, Grant No. 4 T09A 200 25.

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