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Abstract
Patterned Self‐Assembled Monolayers (SAMs) promoting both homeotropic and planar degenerate alignment of 6CB and 9CB in their nematic phase were created using microcontact printing of functionalized organothiols on gold films. The effects of a range of different pattern geometries and sizes were investigated, including stripes, circles and checkerboards. Evanescent wave ellipsometry was used to study the orientation of the liquid crystal (LC) on these patterned surfaces during the isotropic‐nematic phase transition. Pretransitional growth of a homeotropic layer was observed on 1 µm homeotropic aligning stripes, followed by a homeotropic monodomain state prior to the bulk phase transition. Accompanying Monte Carlo simulations of LCs aligned on nanoscale‐patterned surfaces were also performed. These simulations also showed the presence of the homeotropic monodomain state prior to the transition.
Acknowledgments
This work was supported by the Engineering and Physical Research Council, grant Nos. GR/S59826/01 and GR/S59833/01, and the British Council's Treaty of Windsor programme. JPB acknowledges Sharp Laboratories of Europe, Ltd for the provision of a CASE award.
