Synthesis and mesomorphic properties of unsymmetrical banana-shaped 1,3-dihydroxybenzene esters

S. I. Maksimenko Physico-Chemical Institute by A.V. Bogatskiy name of the National academy of sciences of Ukraine, Lustdorfskay doroga, 86, Odessa, 65080, Ukraine

E. Gorecka Department of Chemistry, Warsaw University, ul. Żwirki i Wigury 101, 02-089, Warsaw, Poland

N. S. Novikova Physico-Chemical Institute by A.V. Bogatskiy name of the National academy of sciences of Ukraine, Lustdorfskay doroga, 86, Odessa, 65080, UkraineCorrespondence[email protected]

R. V. Kondratyeva Physico-Chemical Institute by A.V. Bogatskiy name of the National academy of sciences of Ukraine, Lustdorfskay doroga, 86, Odessa, 65080, Ukraine

Abstract

The novel asymmetrical banana-shaped compounds – esters of 1,3-dihydroxybenzene and 4-substituted benzoic acids – have been synthesised. Dependent on the length of the molecular branches either B₂ or B₁ phase has been observed. The introduction of the polar substituent at one of the lateral fragments destabilises the mesomorphic properties.

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Synthesis and mesomorphic properties of unsymmetrical banana-shaped 1,3-dihydroxybenzene esters

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Synthesis and mesomorphic properties of unsymmetrical banana-shaped 1,3-dihydroxybenzene esters

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