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Invited Article

Dynamic self-assembly of nanoparticles using thermotropic liquid crystals

, , , &
Pages 2391-2409 | Received 09 May 2016, Published online: 06 Sep 2016
 

ABSTRACT

3D nanoparticle-based materials with reconfigurable structure have gained vast attention due to the unique possibility of tailoring nanoparticle-related quantum confinement effects. These properties make active nanoparticle assemblies promising candidates for future optoelectronic and metamaterial technologies; however, integration of these materials into real-world applications is still challenging. In this context, the use of stimuli responsive liquid-crystals (LCs) offers a fascinating and industrially feasible strategy for active directing of NPs. Here, we briefly review LCs/NPs hybrid systems in which dynamic behaviour is achieved by affecting either LC matrix or LC ligands. We also experimentally evaluate a complementary strategy based on directly affecting metallic core of LC-covered NPs in an Ostwald ripening process.

GRAPHICAL ABSTRACT

Acknowledgements

This work was supported by the Polish National Science Center under SONATA [Grant number 2013/09/D/ST5/03875].

Disclosure statement

No potential conflict of interest was reported by the authors.

Supplemental data

Supplemental data for this article can be accessed here.

Additional information

Funding

This work was supported by the Polish National Science Center under SONATA [Grant number 2013/09/D/ST5/03875].

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