Li⁺³ ion beam irradiation induced changes in the thermodynamic and electrical parameters of 4-n-(nonyloxy) benzoic acid

ABSTRACT

Li⁺³ ion beam irradiation studies on 4-n-(nonyloxy) benzoic acid (NOBA) have been carried out. Thermodynamic measurements demonstrate that all the phase transition temperatures are depressed for low value of irradiation fluence as compared to those for the pure NOBA and thereafter increase linearly with increase in irradiation fluence. It has also been observed that the temperature range of N and SmC phases in the heating and cooling cycles is improved due to irradiation. Dielectric investigations show that both the transverse as well as the longitudinal components of the dielectric permittivity are increased as compared with those of the pure sample due to irradiation. The observed change in the thermodynamic and dielectric parameters is attributed to the increased concentration of NOBA monomers over the NOBA dimers due to fragmentation of the hydrogen bonding in some of the NOBA dimers.

Graphical Abstract

KEYWORDS:

• Li⁺³ ion beam irradiation
• Liquid crystalline materials
• Thermodynamic parameters
• Dielectric permittivity

Disclosure statement

No potential conflict of interest was reported by the authors.