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Article

Electro-optical response of polymer-dispersed liquid crystals doped with γ-Fe2O3 nanoparticles

, , , , , , , , , & show all
Pages 855-863 | Received 25 Oct 2021, Accepted 06 Jan 2022, Published online: 27 Jan 2022
 

ABSTRACT

In this paper, the microstructures of the dilute magnetic PDLC films, doped with low concentrations of γ-Fe2O3 nanoparticles, have hardly changed, but their electric-optical responses have distinctly changed. The experimental results show that the threshold voltage and hysteresis decreased with the increasing concentration of γ-Fe2O3 nanoparticles. Furthermore, at the relatively low concentration of γ-Fe2O3 nanoparticles (samples (0) and (1) according to ϕm of 0 and 0.11%), the reciprocity of the rise time increased nonlinearly with the increasing square of the applied voltage. However, at the relatively high concentration of γ-Fe2O3 nanoparticles (samples (2) according to ϕm = 0.15%), the reciprocity of the rise time increased linearly with the square of the applied voltage. Moreover, the reciprocity of the decay time was independent of the applied voltage and decreased with increasing the concentration of γ-Fe2O3 nanoparticles. These characteristics are due to the adsorption of free ions by γ-Fe2O3 nanoparticles. As a result, the interfacial interaction between liquid crystal droplets and the polymer matrix decreased, and the effective electric field inside the liquid crystal droplets increased.

Graphical abstract

Disclosure statement

No potential conflict of interest was reported by the author(s).

Supplementary material

Supplemental data for this article can be accessed here.

Additional information

Funding

This work was supported by Fundamental Research Funds for the Central Universities [grant number 2021YJS143], Doctoral Foundation of Southwest University [grant number SWU115010], Natural Science Foundation of Chongqing, China [grant number cstc2021jcjy-msxm3226], and National Natural Science Foundation of China [grant number 51735006, U1837206, 51927810], and Beijing Municipal Natural Science Foundation [grant number 3182013].

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