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Original Articles

Thermodynamic properties of solution by gas chromatography using a liquid crystal as solvent: cholesteryl myristate

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Pages 175-180 | Received 09 May 1988, Accepted 03 Aug 1988, Published online: 24 Sep 2006
 

Abstract

Thermodynamic properties of several organic compounds at infinite dilution in the three phases exhibited by cholesteryl myristate were determined from gas chromatographic data. Activity coefficients for the solutes are reported for the smectic A (74°C), cholesteric (80°C) and isotropic (86°C) phases of the liquid crystal. Excess solution thermodynamic properties are calculated and the results discussed in relation to solute-solvent interactions and orientations of the liquid crystal.

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