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Sixteen new side chain liquid polysiloxanes, either homopolymers derived from poly(hydrogenmethyl)siloxane or copolymers derived from poly(hydrogenmethyl-dimethylsiloxane), are reported with side chains carrying fluoro-substituents. The known effects of fluoro-substitution in low molar mass liquid crystals are strongly echoed in the polymeric analogues and interesting comparisons are made between homo- and co-polymers carrying the same fluorinated side chains.
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