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Original Articles

X-ray investigation of combined main-chain/side-chain liquid-crystalline polymers

, , , &
Pages 721-729 | Received 19 Jun 1989, Accepted 03 Nov 1989, Published online: 24 Sep 2006
 

Abstract

Structural investigations on six combined liquid-crystalline polymers using the X-ray technique are described. The measurements have allowed a characterization of the liquid-crystalline phases and have led to our first ideas about the phase structures. All mesogenic groups are arranged parallel to each other, the shortest segment in the main-chain or in the side-chain determines the smectic layer spacing. A modified designation for liquid-crystalline phases of high polymers is proposed.

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