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Original Articles

Magnetomesogens: Bis(1,3-di(4′-decoxyphenyl)propane-1,3-dionato)oxovanadium (IV)

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Pages 581-584 | Received 22 Apr 1991, Accepted 28 May 1991, Published online: 24 Sep 2006
 

Abstract

β-Diketonate complexes of oxovanadium (IV) have been synthesized and their mesomorphic behaviour investigated. The title complex exhibits a short range monotropic columnar discotic phase, identified by its optical texture and by miscibility studies. The optical texture of the phase is retained on cooling to the crystal. As a consequence of the unpaired electron on vanadium the complexes are paramagnetic.

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