Discotic charge transfer twins Structure and mesophase behaviour of covalently linked triphenylenes and trinitrofluorenones

Abstract

Discotic charge transfer twins, a novel class of discotic liquid-crystalline compounds were studied. These compounds consist of triphenylene units (as donors) which are chemically linked via flexible spacers of various lengths to trinitrofluorenone units (acting as acceptor). They display a liquid-crystalline phase over a wide temperature range extending up to 240–260°C. Based on X-ray analysis a structural model is proposed for the liquid-crystalline phase: the molecules are arranged in columns in such a way that mixed stacks occur, the intercolumnar packing possesses an orthorhombic symmetry. The neighbouring columns are connected along specific directions via flexible spacers which give rise to highly anisotropic structural properties of this columnar liquid-crystalline phase.