Monodomain liquid crystalline networks: reorientation mechanism from uniform to stripe domains

Abstract

Monodomain acrylate-based networks have been synthesized by a two-step cross-linking procedure using gamma-irradiation. Strain-induced reorientation of the nematic director is studied by X-ray diffraction measurements. The geometrical shape (aspect ratio) of the monodomain films is found to affect drastically the dynamics and mechanics of the reorientation transition. Uniform continuous rotation of the director occurs in narrow samples with an aspect ratio AR=12 when the external mechanical field is applied perpendicular to the initial orientation. Under the same conditions, films having a lower aspect ratio (AR=2.5) demonstrate the formation of stripe domains with an alternating sense of director rotation (clockwise and counter-clockwise towards the stress axis). Deformation of a square film (AR=1) generates stripe domains in the geometrical centre of the sample, whereas a uniform continuous rotation is observed in other regions of the film. Finally, a comparison of experimental data and theoretical predictions is presented and discussed.