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Original Articles

1H- and 13C-NMR Studies on Phenol-Formaldehyde Prepolymers for Tannin-Based Adhesives

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Pages 201-217 | Published online: 23 Oct 2006
 

Abstract

The number average structure and the molecular weight distribution of phenol-formaldehyde prepolymers for use in synthesis of tannin-based adhesive resins were determined with 1H- and 13C-NMR spectroscopy and gel permeation chromatography of acetylated resins. These methods were used to determine differences in phenol-formaldehyde prepolymens prepared under different reaction conditions. Quantitative 13C-NMR techniques provided a detailed analysis of the structure of a phenol-formaldehyde prepolymer.

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