Laser-Induced Fluoresence of Lignins with Excitation from 457 to 621 Nanometers

Abstract

Laser-induced fluorescence has been used to examine changes in lignin and black liquor during the course of kraft pulping. When excited with a laser at 457 and 488 nm, lignin samples isolated during the course of pulping, purified, and redissolved in alkali exhibited increasing fluorescent emission intensity. This may be explained by changes in lignin structure during pulping. At higher excitation wavelengths, differences between samples diminished. Black liquors showed decreasing fluorescent intensity with increasing pulping. We attribute this behavior to the increase in optical density of the liquors as cooking time proceeds. The optical density increases with cooking time proceeds. The optical density increases with cooking time because greater amounts of lignin and other materials dissolve from the wood and enter the black liquor.