Measurement of size-dependent dynamic shape factors of quartz particles in two flow regimes

ABSTRACT

Understanding and modeling the behavior of quartz dust particles, commonly found in the atmosphere, requires knowledge of many relevant particle properties, including particle shape. This study uses a single particle mass spectrometer, a differential mobility analyzer, and an aerosol particle mass analyzer to measure quartz aerosol particles mobility (d_m), vacuum aerodynamic, and volume equivalent diameters, mass, composition, effective density, and dynamic shape factor as a function of particle size, in both the free molecular and transition flow regimes. The results clearly demonstrate that dynamic shape factors can vary significantly as a function of particle size. For the quartz samples studied here, the dynamic shape factors increase with size, indicating that larger particles are significantly more aspherical than smaller particles. In addition, dynamic shape factors measured in the free-molecular (χ_v) and transition (χ_t) flow regimes can be significantly different, and these differences vary with the size of the quartz particles. For quartz, χ_v of small (d_m < 200 nm) particles is 1.25, while χ_v of larger particles (d_m ∼ 440 nm) is 1.6, with a continuously increasing trend with particle size. In contrast, χ_t of small particles starts at 1.1 increasing slowly to 1.34 for 550 nm diameter particles. The multidimensional particle characterization approach used here goes beyond determination of average properties for each size, to provide additional information about how the particle dynamic shape factor may vary even for particles with the same mass and volume equivalent diameter.

© 2016 American Association for Aerosol Research

EDITOR:

• Jian Wang

Funding

This work was funded in part by the National Science Foundation under Grant ATC1439045 (J.A., P.K., and V.G.). Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the view of the National Science Foundation. Work by A. Z. and the development of the advanced single particle analysis methods (A.Z.) were supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences & Biosciences. The research was performed using EMSL, a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.