Abstract
A theoretical treatment of the formation and growth of aerosols in systems where condensable molecules are generated at a constant rate is presented. Previous investigations of this type have focused either on collision-controlled (coagulation-limited) nucleation or on condensation /evaporation-controlled nucleation. In the latter case, classical nucleation theory has typically been used to determine particle formation rates, and coagulation of subcritical clusters is neglected. The present theory accounts for both coagulation and condensation / evaporation processes, and serves to bridge the gap between the two limiting cases. The aerosol population balance equations are cast in a nondimensional form and are solved numerically for the time-dependent size spectrum. A key aspect of this work is the identification of dimensionless parameters that have a significant influence on aerosol formation. The most important of these parameters is the evaporation parameter, E =
*This is Particle Technology Laboratory Publication No. 640.
Notes
*This is Particle Technology Laboratory Publication No. 640.