Simultaneous determination of inorganic arsenic, antimony, selenium and tellurium by ICP-MS in environmental waters using SPE preconcentration on modified silica

Abstract

This paper deals with a simplified multi-element profiling of inorganic arsenic, antimony, selenium and tellurium in the form of ⁷⁵As, ⁸²Se, ¹²¹Sb and ¹²⁵Te by ICP-MS for amounts less than 10 µg L⁻¹. Internal standards such as ⁷²Ge and ²⁰⁹Bi were successfully used for the suppression of both influence of macro elements Na⁺, K⁺, Ca²⁺, Mg²⁺ or Al³⁺, and interference of limited concentrations of heavy metal ions. Modified silica sorbents Separon™ SGX C18, C8, CN, NH₂, RPS and Phenyl were tested for the preconcentration of As, Sb, Se and Te (0.25–5 µg L⁻¹) in the form of ion associates with cationic surfactants from 50–250 mL sample volume. 1-etoxycarbonyl-pentadecyltrimethylammonium bromide (Septonex®, 0.005 mol L⁻¹) was suitable for this purpose in the presence of 4-(2-pyridylazo) resorcinol, 2-pyrrolidinecarbodithioate and 8-hydroxyquinoline-5-sulphonic acid. The quantitative retention occurred at pH 7 ± 0.2 and the mixture of acetone with ethanol in ratio 1 : 1 in the presence of 0.1 mol L⁻¹ HCl was used for the quantitative elution. Organic solvents and the excess of acid were removed by evaporation prior to the determination by ICP-MS. The determination of the above trace metalloids in various kinds of water with enrichment factor till 50 times on silica Separon™ SGX C18 and the above reagents were compared with the standard addition method.

Keywords:

• arsenic
• antimony
• selenium
• tellurium
• solid-phase extraction (SPE)
• ICP-MS, waters

Acknowledgement

Financial support from the Ministry of Education, Youth and Sports of the Czech Republic under the 0021622412 MŠMT grant is greatly appreciated.