172
Views
20
CrossRef citations to date
0
Altmetric
Original Articles

Speciation and determination of iron using dispersive liquid–liquid microextraction based on solidification of organic drop followed by flame atomic absorption spectrometry

, , , &
Pages 348-355 | Received 13 Mar 2013, Accepted 28 Aug 2013, Published online: 26 Sep 2013
 

Abstract

A simple and efficient method for iron speciation (Fe2+, Fe3+) using dispersive liquid–liquid microextraction based on solidification of organic drop (DLLME-SFO) technique followed by flame atomic absorption spectrometry was developed. In this method, 1 mL of ethanol (as the disperser solvent) containing 50 µL of 1-undecanol (as the extracting solvent) was injected rapidly into the sample solution containing iron (II), iron (III) species and 1.1 × 10−3 mol L−1 oxine (as the complexing agent). The procedure is based on the complexation of Fe3+ with 8-hydroxyquinoline (oxine) at pH 3, and extraction of the resulting complex using DLLME-SFO. The total Fe was determined after the oxidation of Fe2+ to Fe3+ with concentrated nitric acid. The concentration of Fe2+ was determined from the difference between the concentration of total Fe and the Fe3+. Some parameters such as pH, oxine concentration, ratio of disperser and extractant solvent were investigated. Under the optimum conditions, the calibration graph was linear in the range of 25–250 µg L−1 for Fe3+ with a limit of detection (LOD) of 4.8 µg L−1. The relative standard deviation (RSD, %) for 10 replicate determinations of Fe3+ at 50 µg L−1 levels was 3.2%. To validate the developed method, a certified reference material (BRGM R52) was analysed and the determined value was in very good agreement with the certified value. The proposed method was successfully employed for determination of iron species in tap, well and spring water samples.

Acknowledgement

The authors wish to thank the Ferdowsi University of Mashhad for the financial support of this project.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.