Controlled release of acetochlor from poly (butyl methacrylate-diacetone acrylamide) based formulation prepared by nanoemulsion polymerisation method and evaluation of the efficacy

Abstract

Acetochlor is an important herbicide for gramineous weeds and some small seed broadleaf weeds. Controlled-release formulations of herbicide are highly desirable not only for attaining the most effective utilisation of the weed control, but also for reducing environmental pollution. Acetochlor was incorporated in poly (butyl methacrylate-diacetone acrylamide) based formulation to obtain controlled release properties. The acetochlor nanocapsules were characterised by size distribution, infrared spectroscopy (IR) and field emission scanning electron microscopy (FESEM), and factors related to loading efficiency, swelling behaviour of the formulation were investigated. For this controlled-release formulation, the loading efficiency could reach about 50% (w/w). n, the diffusion parameter was indicative of the transport mechanism, and the values for ‘n’ were in the range of 0.28–0.61, which indicated that the release of acetochlor was diffusion-controlled. The time taken for 50% of the active ingredient to be released into water, t₅₀, was also calculated for the comparison of formulations in different conditions. The formulation with higher temperature and more diacetone acrylamide had lower value of t₅₀, which means a quicker release of the active ingredient. This study highlighted some pieces of evidence that improved herbicide incorporation and slower release were linked to potential interactions between the herbicide and the polymer.

Keywords:

• acetochlor nanocapsules
• controlled release
• poly (butyl methacrylate-diacetone acrylamide)
• efficacy
• preparation

Acknowledgements

This work was supported by The National High Technology Research and Development Program of China (863 Program) (2011AA10A201), China Natural Science Foundation (31301717), China Postdoctoral Science Foundation (2012M511892), China Postdoctoral Science special Foundation (2013T60833), Chongqing Postdoctoral Science special Foundation (XM2012003), and Southwest Postdoctoral Foundation (111669).