ABSTRACT
Uncontrolled use of pesticides could result in contamination of air, water, food, and ecosystems. This study aimed to determine pesticide residues in fruits and vegetables collected from selected farmlands of southwest Ethiopia from the end of April 2019 until mid of May 2019. The samples were extracted using a quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction and clean-up method. Quantitative analysis of four organophosphorus pesticides (OPPs) and seven organochlorine pesticides (OCPs) were conducted using gas chromatography-mass spectrometry. All the fruit and vegetable samples obtained from all sampling sites were contaminated with one or more pesticide residues. Chloroflurenol-methyl was the most predominantly detected OPPs residue in all crop samples obtained from different sampling sites, with a maximum concentration of 0.402 mg kg−1 in potato samples obtained from the Gurafarda site and a minimum value of 0.049 mg kg−1 in onion samples obtained from the South Bench site. Dibutyl chlorendate was the predominant OCPs in all samples, with the minimum value of 0.498 mg kg−1, which was detected in tomato samples collected from the Jamo site, and the maximum concentration of 1.003 mg kg−1 detected in pineapple samples obtained from the North Bench site. Dimethoate concentrations in tomato samples (0.045–0.084 mg kg−1) were above the maximum residue limits (MRLs) established by the European Union (EU) guidelines (0.01 mg kg−1) but were below the MRLs established by Codex Alimentarius Commission (CAC) guidelines (0.5 mg kg−1). Relatively high residue concentrations of dibutyl chlorendate and chloroflurenol-methyl were detected in all the samples obtained from all sampling sites. There is widespread use of pesticides for agriculture by the producers in the study area and there is a need for the regular monitoring of pesticide residues.
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Acknowledgments
The authors acknowledge Mizan-Tepi University for material support. In addition, the authors express their appreciation and thanks to Mizan-Tepi University research and community service directorate for overall facilities during the survey. Lastly, the researchers would like to extend their deepest thanks to JIJE Analytical Testing Service Laboratory assistants in Addis Ababa for their unreserved support.
Author contributions
J.S. wrote the protocol and participated in data collection and experimental work, F.E. analyzed the data and wrote the manuscript. J.S. and F.E. performed manuscript editing. Both authors have read and agreed to the published version of the manuscript.
Data availability statement
The data that support the findings of this study are available from the corresponding author up-on reasonable request.
Disclosure statement
No potential conflict of interest were disclosed by the author.
Institutional review board statement
‘Not applicable’.
Informed consent statement
‘Not applicable’.
Sample availability
Samples of the compounds analyzed in the study are available from the author’s up-on reasonable request.