Abstract
An improved procedure for the determination of 222Rn and 226Ra in seawater developed for easier on-board operations is presented. Data on the radioactive disequilibrium between the mentioned radionuclides as directly determined in the field can be greatly helpful in the study of the gas-exchange processes at the air-sea interface, especially as far as the Antarctic Ocean is concerned. The method employed has been preliminarly tested in laboratory on a set of seawater samples collected in the Ross Sea and 226Ra data collected are discussed and compared to literature data.