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Original Articles

POLYHALOGENIERTE ETHANE IN DER KINNEAR-PERREN-REAKTION

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Pages 95-98 | Received 21 Jun 1979, Published online: 19 Dec 2006
 

Abstract

Fluorierte Ethane (Refrigerants) werden mit AlCl3 und PCl3 bzw. CH3PCl2 umgesetzt. Unter vollständiger Defluorierung werden polychlorierte Phosphon- und Phosphinsäuerechloride erhalten. Eine Umsetzung mit AlBr3 und PBr3 führt zu Haloethyldibromphosphanen.

Fluorinated ethanes (Refrigerants) were caused to react with AlCl3 and PCl3 of CH3PCl2 resp. Complete defluorination led to polychlorinated phosphonicdichlorides and phosphinicchlorides. Reactions with AlBr3 and PB3 produced halogenated ethyldibromophosphines.

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