SYNTHESES A L'AIDE D'HETEROCUMULENES. 3.^† NOUVELLES OXAZOLIDINONES-2 ET IMIDAZOLIDINONES-2 A PARTIR DE L'ISOCYANATE DE PHENOXYSULFONYLE

Mir Hedayatullah Laboratoire de Chimie Organique, CNAM l'Université Paris VII, associé au C.N.R.S., 1, rue Guy de la Brosse, 75005, Paris; Laboratoire de Chimie Organique, Physique de l'Université Paris VII, associé au C.N.R.S., 1, rue Guy de la Brosse, 75005, Paris

Jean François Brault Laboratoire de Chimie Organique, CNAM l'Université Paris VII, associé au C.N.R.S., 1, rue Guy de la Brosse, 75005, Paris

Abstract

Nous rapportons ici, la première utilisation en synthèse hétérocyclique de l'isocyanate de phénoxysulfonyle, un hétérocumulène simple d'accès, qui réagit avec les ω-halogénoalcools et les β-halogénoéthyl-amines pour fournir une nouvelle famille d'oxazolidinones-2 et d'imidazolidinones-2.

We report here, the first use in heterocyclic synthesis of the phenoxysulfonyl isocyanate that reacts with ω-halogeno-alcools and β-halogeno-ethylamines to give a new family of 2-oxazolidinones and 2-imidazolidinones.

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SYNTHESES A L'AIDE D'HETEROCUMULENES. 3.^† NOUVELLES OXAZOLIDINONES-2 ET IMIDAZOLIDINONES-2 A PARTIR DE L'ISOCYANATE DE PHENOXYSULFONYLE

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SYNTHESES A L'AIDE D'HETEROCUMULENES. 3.† NOUVELLES OXAZOLIDINONES-2 ET IMIDAZOLIDINONES-2 A PARTIR DE L'ISOCYANATE DE PHENOXYSULFONYLE

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SYNTHESES A L'AIDE D'HETEROCUMULENES. 3.^† NOUVELLES OXAZOLIDINONES-2 ET IMIDAZOLIDINONES-2 A PARTIR DE L'ISOCYANATE DE PHENOXYSULFONYLE