METALLA IVb-PHOSPHOLANNES I. Dimetalla-2,5 Phospholannes, Metalla-2 Diphospholannes-1,3 et Metalla-3 Diphospholannes-1,2

J. D. Andriamizaka Laboratoire de Chimie des Organominéraux, ERA 829 du CNRS, Université P. Sabatier, 118 route de Narbonne, 31062, Toulouse cedex

C. Couret Laboratoire de Chimie des Organominéraux, ERA 829 du CNRS, Université P. Sabatier, 118 route de Narbonne, 31062, Toulouse cedex

J. Escudié Laboratoire de Chimie des Organominéraux, ERA 829 du CNRS, Université P. Sabatier, 118 route de Narbonne, 31062, Toulouse cedex

J. Satgé Laboratoire de Chimie des Organominéraux, ERA 829 du CNRS, Université P. Sabatier, 118 route de Narbonne, 31062, Toulouse cedex

Abstract

We present the synthesis of novel sila-, germa- and stanna-phospholanes: 2,5-dimetallaphospholanes, 2-metalla 1,3-diphospholanes and 3-metalla 1,2-diphospholanes. Preparation and characterization reactions of the first stable diphosphorus germylene are also described.

Nous décrivons dans ce mémoire la synthèse de nouveaux sila- germa- et stannaphospholannes: dimétalla-2,5 phospholannes, métalla-2 diphospholannes-1,3 et métalla-3 diphospholannes-1,2. Nous exposons également la préparation et les réactions de caractérisation du premier germylène diphosphoré stable.

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METALLA IVb-PHOSPHOLANNES I. Dimetalla-2,5 Phospholannes, Metalla-2 Diphospholannes-1,3 et Metalla-3 Diphospholannes-1,2

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METALLA IVb-PHOSPHOLANNES I. Dimetalla-2,5 Phospholannes, Metalla-2 Diphospholannes-1,3 et Metalla-3 Diphospholannes-1,2

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