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Phosphorus and Sulfur and the Related Elements Volume 14, 1983 - Issue 3
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Original Articles

CATIONS PHOSPHORES A BASSE COORDINATION: LES IMINOPHOSPHENIUMS N[sbnd]p[sbnd]N[dbnd]NR

M. Sanchez Equipe de Recherche Associée au CNRS No. 926, Laboratoire des Hétérocycles du Phosphore et de l′Azote, Université Paul Sabatier, 31062, Toulouse Cedex
,
M. R. Marre Equipe de Recherche Associée au CNRS No. 926, Laboratoire des Hétérocycles du Phosphore et de l′Azote, Université Paul Sabatier, 31062, Toulouse Cedex
,
J. F. Brazier Equipe de Recherche Associée au CNRS No. 926, Laboratoire des Hétérocycles du Phosphore et de l′Azote, Université Paul Sabatier, 31062, Toulouse Cedex
,
J. Bellan Et Equipe de Recherche Associée au CNRS No. 926, Laboratoire des Hétérocycles du Phosphore et de l′Azote, Université Paul Sabatier, 31062, Toulouse Cedex
&
R. Wolf Equipe de Recherche Associée au CNRS No. 926, Laboratoire des Hétérocycles du Phosphore et de l′Azote, Université Paul Sabatier, 31062, Toulouse Cedex
Pages 331-334 | Received 24 Sep 1982, Published online: 13 Dec 2006
 
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Abstract

The novel iminophosphenium, [(CH3)2N]2 P+=NC6H5, has been prepared by a modified Staudinger reaction. The mechanism of this process is discussed on the basis of spectroscopic studies of various derivatives of this ion.

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