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Phosphorus and Sulfur and the Related Elements Volume 14, 1983 - Issue 3
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Original Articles

STRUCTURES CRISTALLINES, ETUDES VIBRATIONNELLES ET PROPRIETES COMPLEXANTES DE DITHIOXODI-λ5-PHOSPHANES (DISULFURES DE DIPHOSPHINES) DIALCOYLAMINES ET PHENYLES

Danielle Troy Et Laboratoire de Chimie de Coordination, CNRS, 205, route de Narbonne, 31400, Toulouse
&
Jean-Pierre Legros Laboratoire de Chimie de Coordination, CNRS, 205, route de Narbonne, 31400, Toulouse
Pages 377-380 | Received 24 Sep 1982, Published online: 13 Dec 2006
 
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Abstract

The alkylamino or phenyl-substituted dithioxodi-λ5-phosphanes occur in the centrosymmetric trans conformation in the solid state as well as in solution. Complexes were obtained with Cu(I), Pd(II) and Pt(II). The coordination takes place through the sulfur atoms and five-membered chelate rings are formed.

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