A DIRECT SYNTHESIS OF 1-CYCLOALKENYLPHOSPHONATES

Shyamal Banerjee Doctoral Program in Chemistry, The City University of New York, Queens College, Flushing, NY, 11367

Robert Engel Doctoral Program in Chemistry, The City University of New York, Queens College, Flushing, NY, 11367

George Axelrad Doctoral Program in Chemistry, The City University of New York, Queens College, Flushing, NY, 11367

Abstract

A series of 1-cycloalkenylphosphonate diesters has been synthesized starting with the corresponding vinylic chlorides. This has been accomplished using the Cu(I) complexes of triethyl phosphite in a direct reaction with the vinylic chlorides. This represents a convenient method for the synthesis of this class of compounds previously requiring multi-step routes.

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A DIRECT SYNTHESIS OF 1-CYCLOALKENYLPHOSPHONATES

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A DIRECT SYNTHESIS OF 1-CYCLOALKENYLPHOSPHONATES

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