Transition Metal Substituted Phosphanes: Synthesis, Reactivity and Pyramidal Inversion

W. Malisch Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

R. Maisch Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

A. Meyer Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

D. Greissinger Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

E. Gross Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

I. J. Colquhoun Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

W. McFarlane Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

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Abstract

The synthesis of transition metal substituted phosphanes C₅H₅(CO)₂M-PPh₂, C₅H₅(CO)₂(Me₃P)M-PPh₂ (M [dbnd] Mo, W) and C₅H₅(CO)(Me₃P)FePPhR (R [dbnd] Me, Ph) is described as well as their reactivity towards a series of electrophilic and oxidizing reagents.

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Transition Metal Substituted Phosphanes: Synthesis, Reactivity and Pyramidal Inversion

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Transition Metal Substituted Phosphanes: Synthesis, Reactivity and Pyramidal Inversion

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