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The interaction between dialkyl phosphites (RO)2P(O)H where R = CH3, C2H5, C4H9 and metal salts MeX2 where Me [dbnd] Zn, Ca, Co, Mn, Cd and X = Cl, NO3 and CH3COO was studied. It was found that the reaction depends on the substitutes in the dialkyl phosphites as well as on the nucleophilicity of the metal salts. The monoalkyl phosphorous acid esters of the following general formula were obtained:
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