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Phosphorus and Sulfur and the Related Elements Volume 19, 1984 - Issue 3
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Original Articles

A FACILE CONVERSION OF SULFOXIMINES AND SULFONEDIIMINES TO SULFOXIDES AND SULFILIMINES WITH TERT-BUTYL NITRITE

Kunihiko Akutagawa Department of Chemistry, The University of Tsukuba, Sakura-mura, Niihari-gun, Ibaraki, 305, Japan
,
Naomichi Furukawa Department of Chemistry, The University of Tsukuba, Sakura-mura, Niihari-gun, Ibaraki, 305, Japan
&
Shigeru Oae Department of Chemistry, The University of Tsukuba, Sakura-mura, Niihari-gun, Ibaraki, 305, Japan; Okayama University of Science, Ridai-cho, 1–1, Okayama, 700, Japan
Pages 369-374 | Received 23 Sep 1984, Accepted 12 Jan 1984, Published online: 19 Dec 2006
 
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Abstract

N-Unsubstituted sulfoximines and N-mono-tosylsulfonediimines were found to react readily with tert-butyl nitrite to give the corresponding sulfoxides and N-tosylsulfilimines in high yields with no racemization.

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